Cooling Tower Water Analysis

Cooling Tower Water Analysis: Complete Guide

Analyzing cooling tower water is an essential step to maintain system performance and prevent physico-chemical or biological drift. Cooling towers play a central role in industrial heat rejection, but their operation depends on the stability of the circulating water.
This article presents the key parameters, analytical methods and tools to optimize your in-house monitoring.

Tour aéroréfrigérante industrielle, installation concernée par l’analyse de l’eau circulante en circuit de refroidissement.

Why analyze cooling tower water regularly?

Cooling towers cool industrial equipment by dissipating heat into ambient air. Their operation relies on a delicate balance between water quality, thermal efficiency and biological stability. Regular cooling tower water analysis is necessary to meet regulatory requirements, limit health risks, especially those related to Legionella, and preserve the overall efficiency of the installation. Analytical monitoring helps confirm that this balance is maintained and enables early detection of any treatment drift.

Schéma de principe illustrant l’analyse de l’eau en tour de refroidissement.

Cooling system diagram

A cooling tower operates on a recirculation principle: hot water from the industrial process is sent to the tower, sprayed, then cooled through contact with ambient air before being returned to the circuit.
Understanding this circuit helps identify where losses, evaporation, deposits or corrosion phenomena occur, and supports the definition of appropriate monitoring frequencies.

(Cooling tower water analysis diagram | AQUALABO)

Understanding cooling tower efficiency

A tower’s thermal performance can be assessed based on the cooling achieved between inlet and outlet temperatures: (Inlet temperature – Outlet temperature = ΔT).

  • Performance calculation (ΔT) = (Evaporation x 660) / (Circulation flow rate)

  • Evaporation = Make-up water – Blowdown

  • Blowdown = Make-up water / Concentration

You need to know your make-up water (meter reading), your concentration (via chloride analysis if chlorine dosing is not too high), and the circulation flow rate (pump data). The average thermal performance of cooling towers is 5°C. Evaporation can be estimated, and blowdown can then be derived.

Schéma technique d’une tour de refroidissement utilisé pour l’analyse de l’eau du circuit.

Major risks in cooling towers

Cooling towers expose water to conditions that simultaneously promote three major risks: corrosion, scaling and microbiological growth. None of these can be monitored independently, as they influence each other. This is why regulations related to Legionella risk require comprehensive physico-chemical monitoring.

Among these microorganisms, Legionella is a bacterium naturally present in aquatic environments that can develop in warm water when conditions are favorable. In a cooling tower, it can proliferate if water conditions are not properly controlled and may then be dispersed into the air as aerosols during tower operation.

To limit this health risk, regulations require regular physico-chemical monitoring of the water, in addition to microbiological surveillance. Monitoring key parameters helps maintain conditions unfavorable to Legionella growth, verify the effectiveness of applied treatments, and ensure sanitary compliance of installations.

Which parameters should be monitored in a cooling tower water analysis?

Analytical monitoring of a cooling tower relies on a set of complementary physico-chemical parameters. Each provides specific information about water condition, treatment behavior and the overall balance of the circuit. The parameters detailed below form the basis of routine monitoring, directly usable by operators and technicians responsible for cooling tower follow-up. Depending on tower configuration or treatment requirements, additional parameters may also be measured.

Total hardness (TH)

High hardness promotes scale formation on heat exchangers, reducing thermal efficiency and potentially interfering with certain chemical treatments. Its evolution directly reflects salt accumulation due to evaporation and indicates scaling risk on heat transfer surfaces.
Regular monitoring of hardness helps adjust blowdown and assess whether anti-scale treatments remain appropriate for actual operating conditions.

Measure water hardness quickly and easily to adjust your systems or perform on-site checks.

Phenolphthalein P-Alkalinity & Total Alkalinity (M o Methyl Orange)

Measuring alkalinity helps anticipate pH variations and identify imbalances that may lead either to corrosion or to salt precipitation. This parameter is essential for correctly interpreting pH trends and adjusting treatments.

pH

pH plays a central role in the chemical balance of a cooling tower. It affects the performance of inhibitors, biocides and dispersants, and directly influences corrosion and scaling. Monitoring pH helps verify the overall consistency of the treatment program and quickly detect chemical drift before equipment is impacted.

Iron

Iron presence is a common indicator of internal corrosion. Monitoring helps confirm a diagnosis supported by other parameters (pH, alkalinity) and detect premature material degradation or ineffective corrosion inhibition before the issue becomes visible or critical.

Chlorides

Chlorides are used as a reference parameter to calculate concentration cycles. Measuring chlorides helps control blowdown and manage water concentration in the circuit. They also act as an alert signal for corrosion risk when levels become too high, especially for certain sensitive materials.

Tour de refroidissement industrielle intégrée à un site de production

Cooling tower water analysis: recommended frequencies

Each parameter requires regular monitoring depending on its role in circuit supervision:

 

Parameter

Raw Water

Make-up Water

Cooling Tower

Closed loop

Ca++

M

D

D

 

Total Hardness

W

D

D

W

P-Alkalinity

  

D

W

M-Alkalinity

W

D

D

W

Cl-

W

D

D

 

Iron

W

D

D

W

Cu++

  

W

W

Chlorine

W

D

D

 

Triazole

  

W

W

Phosphonates / Polyacrylates

  

D

 

pH

W

D

D

W

Cond. µS/cm

W

D

D

W

Temp °C

W

D

D

W

W = weekly, D = daily, M = monthly

Other possible parameters: Nitrite, Molybdenum, Glycol



Conducting internal analyses: equipment and methods

To build a complete analysis kit, Aqualabo provides methods listing essential equipment: volumetric flasks, Erlenmeyer flasks, graduated cylinders, automatic burettes, titrant solutions, color indicators and reagents adapted to each parameter. Our solutions ensure reliable, repeatable monitoring aligned with field requirements.

Equipment for volumetric analysis

Equipment / Parameters

Ca++

Total Hardness

P-Alkalinity

M-Alkalinity

Free Mineral Acidity

Cl⁻

CO₂

Titrant solution

1LC009

1LC009

1LA026

1LA026

1LA008

1AN031

1LA026

Color indicator

1IE001

1IN000

1PT001

1RT004

1H0001

1PC005

1PT001

Preparation reagents

1RA001

1TK004

  

1A0001

 

1LA008

Method No.

303B

302B

305

306B

309

314AG

301

 

 

Flacon et dispositif utilisés pour l’analyse de l’eau en tour de refroidissement.

Erlenmeyer flask 100 ml – 1FE003

Erlenmeyer flask 250 ml – 1FE004

Volumetric flask 50 ml – 1FJ001

Volumetric flask 100 ml – 1FJ002

Plastic graduated cylinder 25 ml – 1EG001

 

Use one burette per titrant solution

  • Automatic burette, direct reading 0 to 30 °f – 1BZ001
  • Automatic burette in ml 0 to 15 ml – 1BZ000

Schilling burette 0 to 25 ml – 1BS012

 

Burette Hardness Method – Aqualabo 

Burette Method – Alkalinity  

Equipment for colorimetric analysis

 

Parameters

Kits

Test strips

Chlorine

1KC001

 

Sulfates

FMN931092 (Turbidity)

FMN91320

Quaternary ammonium

1KA018

 

Molybdates

 

1PI325

Nitrites

 

1PI322

 



image3 (1)

ORCHIDIS comparator – 1CH003

 

One pair of A/B cuvettes – 1CA005

 

Tour aéroréfrigérante industrielle, installation concernée par l’analyse de l’eau circulante en circuit de refroidissement.

Analyze your cooling tower with Aqualabo to optimize your installation

Water analysis is a key lever to ensure proper cooling tower operation and control physico-chemical drift. Aqualabo offers operators a complete range of kits, reagents and analytical methods adapted to cooling tower constraints. These solutions help effectively monitor scaling, corrosion and biological growth, while supporting decision-making in the field.
Aqualabo teams support industrial sites in selecting methods and analytical equipment to implement reliable, consistent and operational monitoring.

Contact our teams to define the equipment and reagents that match your needs: